🔹 Kinetic Theory of Gases – Stage 1 (Page 4)

1️⃣ Three Important Molecular Speeds

In a gas, molecules do not move with the same speed. Instead, their speeds are distributed over a range.

The three important speeds are:

  • Most Probable Speed (vmp)
  • Average Speed (vavg)
  • Root Mean Square Speed (vrms)

2️⃣ Most Probable Speed (vmp)

The speed possessed by the maximum number of molecules at a given temperature.

vmp = √(2kT / m)

In molar form:

vmp = √(2RT / M)


3️⃣ Average Speed (vavg)

Arithmetic mean of the speeds of all molecules.

vavg = √(8kT / πm)

In molar form:

vavg = √(8RT / πM)


4️⃣ RMS Speed (vrms)

Defined as the square root of the mean of the squares of speeds.

vrms = √(3kT / m)

In molar form:

vrms = √(3RT / M)


5️⃣ Relation Between Speeds (VERY IMPORTANT)

vmp : vavg : vrms = √2 : √(8/π) : √3

Numerically:

vmp < vavg < vrms


6️⃣ Maxwell–Boltzmann Speed Distribution

The Maxwell distribution curve shows how molecular speeds are distributed at a given temperature.

  • Curve is asymmetric
  • Peak corresponds to vmp
  • Area under curve = total molecules

Effect of temperature:

  • Increase in T → curve flattens
  • Peak shifts to right
  • More high-speed molecules

7️⃣ JEE Exam Traps

  • Speeds depend on √T, not T
  • At same T, lighter gas moves faster
  • KE depends on T, speed depends on mass
  • Never confuse speed with kinetic energy

✔ Stage 1 – Page 4 COMPLETE

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