🔹 Kinetic Theory of Gases – Stage 1 (Page 10)
1️⃣ Collision of Gas Molecules
Gas molecules are in continuous random motion and undergo perfectly elastic collisions with each other and with the walls.
- Molecule size is very small compared to distance travelled
- No loss of kinetic energy during collisions
2️⃣ Mean Free Path (λ)
Mean free path is the average distance travelled by a molecule between two successive collisions.
λ = 1 / (√2 π d² n)
where,
- d = diameter of molecule
- n = number density (N/V)
3️⃣ Mean Free Path in Terms of Pressure
λ = kT / (√2 π d² P)
- Mean free path ∝ Temperature
- Mean free path ∝ 1 / Pressure
4️⃣ Collision Frequency (z)
Collision frequency is the number of collisions made by one molecule per second.
z = v̄ / λ
where v̄ = average speed of molecules
- Higher temperature → higher collision frequency
- Higher pressure → higher collision frequency
5️⃣ Mean Collision Time (τ)
Time between two successive collisions:
τ = 1 / z = λ / v̄
6️⃣ Transport Phenomena in Gases
Transport phenomena arise due to random motion of molecules.
- Viscosity
- Thermal conductivity
- Diffusion
7️⃣ Viscosity of Gases
Viscosity is the resistance to relative motion between adjacent layers.
η = (1/3) ρ v̄ λ
- Viscosity of gases increases with temperature
- Almost independent of pressure
8️⃣ Thermal Conductivity
Ability of gas to conduct heat due to molecular motion.
- Increases with temperature
- Independent of pressure
9️⃣ Diffusion
Diffusion is the process by which gas molecules spread from higher concentration to lower concentration.
- Lighter gases diffuse faster
- Rate ∝ 1 / √M
🔟 JEE Advanced Shortcuts & Traps
- Mean free path ∝ T / P
- η, K independent of pressure → common MCQ trap
- Always check proportionality, not exact formula
✔ KTG – Stage 1 COMPLETE (Pages 1–10)
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- KTG – Part 14
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- KTG – Part 17
- KTG – Part 18
- KTG – Part 19
- KTG – Part 20
- KTG – Part 21
- KTG – Part 22
- KTG – Part 23
- KTG – Part 24
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- KTG – Part 26
- KTG – Part 27
- KTG – Part 28
- KTG – Part 29
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- Properties – Part 2
- Properties – Part 3
- Properties – Part 4
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- Properties – Part 7
- Properties – Part 8
- Properties – Part 9
- Properties – Part 10
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