🔹 Kinetic Theory of Gases – Stage 2 (Page 2)
This page explains the Maxwell–Boltzmann speed distribution, one of the most tested concepts in IIT-JEE Advanced.
1️⃣ Why Speed Distribution Exists?
In a gas, molecules continuously collide and exchange energy. Therefore, all molecules cannot have the same speed.
- Some molecules move very slowly
- Some move extremely fast
- Most move around an intermediate speed
2️⃣ Maxwell–Boltzmann Speed Distribution
The distribution gives the number of molecules having speed between v and v + dv.
dN ∝ v² e(−mv² / 2kT) dv
- v² term → number of ways to have speed v
- Exponential term → energy probability
3️⃣ Maxwell Distribution Graph
Graph between Number of molecules (y-axis) and Speed (x-axis).
- Curve starts from zero at v = 0
- Rises to a maximum
- Gradually falls asymptotically
The area under the curve = Total number of molecules.
4️⃣ Characteristic Speeds
Most Probable Speed:
vmp = √(2kT / m)
Average Speed:
v̄ = √(8kT / πm)
RMS Speed:
vrms = √(3kT / m)
5️⃣ Ordering of Speeds (Very Important)
vmp < v̄ < vrms
- Always true for all gases
- Independent of temperature and gas type
6️⃣ Effect of Temperature on Distribution
- Increase in temperature → curve shifts right
- Peak becomes lower and broader
- More high-speed molecules appear
Area under curve remains constant.
7️⃣ Effect of Molecular Mass
- Lighter gas → curve shifts right
- Heavier gas → curve shifts left
- At same T, ⟨KE⟩ is same for all gases
8️⃣ JEE Advanced Trap Box ⚠️
- Average speed ≠ RMS speed
- Higher speed ≠ higher kinetic energy always
- Distribution exists even at constant temperature
9️⃣ Conceptual Check
If temperature doubles:
- vmp, v̄, vrms increase by √2
- Distribution widens
- Area remains same
✔ Stage 2 – Page 2 Completed
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