🔹 Kinetic Theory of Gases – Stage 2 (Page 2)

This page explains the Maxwell–Boltzmann speed distribution, one of the most tested concepts in IIT-JEE Advanced.


1️⃣ Why Speed Distribution Exists?

In a gas, molecules continuously collide and exchange energy. Therefore, all molecules cannot have the same speed.

  • Some molecules move very slowly
  • Some move extremely fast
  • Most move around an intermediate speed

2️⃣ Maxwell–Boltzmann Speed Distribution

The distribution gives the number of molecules having speed between v and v + dv.

dN ∝ v² e(−mv² / 2kT) dv

  • v² term → number of ways to have speed v
  • Exponential term → energy probability

3️⃣ Maxwell Distribution Graph

Graph between Number of molecules (y-axis) and Speed (x-axis).

  • Curve starts from zero at v = 0
  • Rises to a maximum
  • Gradually falls asymptotically

The area under the curve = Total number of molecules.


4️⃣ Characteristic Speeds

Most Probable Speed:

vmp = √(2kT / m)

Average Speed:

v̄ = √(8kT / πm)

RMS Speed:

vrms = √(3kT / m)


5️⃣ Ordering of Speeds (Very Important)

vmp < v̄ < vrms

  • Always true for all gases
  • Independent of temperature and gas type

6️⃣ Effect of Temperature on Distribution

  • Increase in temperature → curve shifts right
  • Peak becomes lower and broader
  • More high-speed molecules appear

Area under curve remains constant.


7️⃣ Effect of Molecular Mass

  • Lighter gas → curve shifts right
  • Heavier gas → curve shifts left
  • At same T, ⟨KE⟩ is same for all gases

8️⃣ JEE Advanced Trap Box ⚠️

  • Average speed ≠ RMS speed
  • Higher speed ≠ higher kinetic energy always
  • Distribution exists even at constant temperature

9️⃣ Conceptual Check

If temperature doubles:

  • vmp, v̄, vrms increase by √2
  • Distribution widens
  • Area remains same

✔ Stage 2 – Page 2 Completed

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