🔥 Thermodynamics – Stage 3

Page 7 : JEE Advanced Mixed PYQs (Numerical + Reasoning)

These problems require concept linking + approximation + logic. Direct formula application will fail.

PYQ 1️⃣ : Variable Pressure Work Trap

Gas expands with pressure varying as P = a − bV.
Work = ∫ P dV = ∫ (a − bV)dV
= a(V₂−V₁) − b(V₂²−V₁²)/2
❌ Using W = PΔV

PYQ 2️⃣ : Half-Cycle Trap

Gas completes half of a cyclic process.
ΔU ≠ 0 (state not repeated)
❌ Assuming cyclic behavior too early

PYQ 3️⃣ : Maximum Work Condition

Gas expands from P₁ to P₂.
Maximum work → Reversible isothermal
❌ Choosing adiabatic for max work

PYQ 4️⃣ : Carnot Engine Reality Check

Engine working between 400K and 300K.
ηmax = 1 − 300/400 = 25%
❌ Expecting real engine efficiency = Carnot

PYQ 5️⃣ : Mixing of Gases Entropy

Two different ideal gases mix.
ΔS > 0 even if temperatures equal
❌ Thinking entropy depends only on temperature

PYQ 6️⃣ : Internal Energy Illusion

Ideal gas compressed isothermally.
ΔU = 0, but Q ≠ 0 and W ≠ 0
❌ Equating ΔU = 0 to no heat transfer

PYQ 7️⃣ : Fast vs Slow Process

Same expansion done fast and slow.
Work differs; final state same
❌ Thinking work is state function

PYQ 8️⃣ : Temperature vs Heat

Two gases absorb equal heat.
ΔT depends on degrees of freedom
❌ Assuming ΔT ∝ Q always

PYQ 9️⃣ : Refrigerator Misconception

Refrigerator removes heat from cold body.
Work input required (always)
❌ Thinking natural heat flow helps refrigerator

PYQ 🔟 : Final JEE Trap Statement

Same ΔT does NOT imply same heat absorbed

✅ Stage 3 – Page 7 Completed
➡️ Next: Stage 3 – Page 8 (Assertion–Reason & Concept Killer Problems)

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