🔥 Thermodynamics – Stage 3
Page 7 : JEE Advanced Mixed PYQs (Numerical + Reasoning)
These problems require concept linking + approximation + logic.
Direct formula application will fail.
PYQ 1️⃣ : Variable Pressure Work Trap
Gas expands with pressure varying as P = a − bV.
Work = ∫ P dV = ∫ (a − bV)dV
= a(V₂−V₁) − b(V₂²−V₁²)/2
= a(V₂−V₁) − b(V₂²−V₁²)/2
❌ Using W = PΔV
PYQ 2️⃣ : Half-Cycle Trap
Gas completes half of a cyclic process.
ΔU ≠ 0 (state not repeated)
❌ Assuming cyclic behavior too early
PYQ 3️⃣ : Maximum Work Condition
Gas expands from P₁ to P₂.
Maximum work → Reversible isothermal
❌ Choosing adiabatic for max work
PYQ 4️⃣ : Carnot Engine Reality Check
Engine working between 400K and 300K.
ηmax = 1 − 300/400 = 25%
❌ Expecting real engine efficiency = Carnot
PYQ 5️⃣ : Mixing of Gases Entropy
Two different ideal gases mix.
ΔS > 0 even if temperatures equal
❌ Thinking entropy depends only on temperature
PYQ 6️⃣ : Internal Energy Illusion
Ideal gas compressed isothermally.
ΔU = 0, but Q ≠ 0 and W ≠ 0
❌ Equating ΔU = 0 to no heat transfer
PYQ 7️⃣ : Fast vs Slow Process
Same expansion done fast and slow.
Work differs; final state same
❌ Thinking work is state function
PYQ 8️⃣ : Temperature vs Heat
Two gases absorb equal heat.
ΔT depends on degrees of freedom
❌ Assuming ΔT ∝ Q always
PYQ 9️⃣ : Refrigerator Misconception
Refrigerator removes heat from cold body.
Work input required (always)
❌ Thinking natural heat flow helps refrigerator
PYQ 🔟 : Final JEE Trap Statement
Same ΔT does NOT imply same heat absorbed
✅ Stage 3 – Page 7 Completed
➡️ Next: Stage 3 – Page 8 (Assertion–Reason & Concept Killer Problems)
➡️ Next: Stage 3 – Page 8 (Assertion–Reason & Concept Killer Problems)
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🔥 Thermodynamics – Objective Final Revision
Thermodynamics – Set 1
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Set 10
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Set 40
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Set 44
Set 45
Set 46
Set 47
Set 48
Set 49
Set 50
Set 51
Set 52
Set 53
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