🔥 Thermodynamics – Stage 2
Page 9 : Carnot Engine & Absolute Temperature Scale
Carnot Engine defines the maximum possible efficiency of any heat engine.
No real engine can cross this limit.
1️⃣ What is a Carnot Engine?
A Carnot engine is an ideal reversible heat engine operating between two heat reservoirs:
🔥 Hot reservoir at temperature T₁
❄ Cold reservoir at temperature T₂
🔥 Hot reservoir at temperature T₁
❄ Cold reservoir at temperature T₂
✔ It gives the maximum efficiency possible between T₁ and T₂.
2️⃣ Carnot Cycle – Four Processes
(i) Isothermal Expansion (at T₁)
Heat absorbed Q₁ from hot reservoir
Heat absorbed Q₁ from hot reservoir
(ii) Adiabatic Expansion
Temperature drops from T₁ to T₂
Temperature drops from T₁ to T₂
(iii) Isothermal Compression (at T₂)
Heat rejected Q₂ to cold reservoir
Heat rejected Q₂ to cold reservoir
(iv) Adiabatic Compression
Temperature rises from T₂ to T₁
Temperature rises from T₂ to T₁
3️⃣ Efficiency of Carnot Engine
Efficiency (η) = Work output / Heat absorbed
ηCarnot = 1 − (T₂ / T₁)
⚠ Temperatures must be in KELVIN
4️⃣ Key Conclusions from Carnot Theorem
- No engine can be more efficient than a Carnot engine
- All reversible engines between same T₁ and T₂ have same efficiency
- Efficiency depends only on temperatures, not on working substance
5️⃣ Absolute Temperature Scale
Carnot efficiency expression led to the definition of absolute temperature.
Absolute zero is the temperature at which:
👉 Carnot efficiency becomes 100%
👉 Carnot efficiency becomes 100%
Absolute zero = 0 K = −273.15 °C
6️⃣ Why 100% Efficiency is Impossible?
For η = 1,
T₂ must be 0 K
T₂ must be 0 K
❌ Absolute zero cannot be reached
❌ Hence 100% efficiency is impossible
7️⃣ JEE Advanced Traps
- Using °C instead of K
- Assuming efficiency depends on engine design
- Thinking real engines can reach Carnot efficiency
- Confusing Carnot engine with refrigerator
8️⃣ Ranker’s One-Line Memory
Carnot engine sets the upper limit
η depends only on T₁ and T₂
Kelvin scale is compulsory
η depends only on T₁ and T₂
Kelvin scale is compulsory
✅ Stage 2 – Page 9 Completed
➡️ Next: Stage 2 – Page 10 : Entropy & Clausius Inequality
➡️ Next: Stage 2 – Page 10 : Entropy & Clausius Inequality
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