🔥 Thermodynamics – Stage 1
Page 9 : Adiabatic Process & Poisson’s Equations (JEE Core)
Adiabatic Process is one of the most frequently tested concepts in JEE.
1️⃣ What is an Adiabatic Process?
ΔQ = 0
• No heat enters or leaves the system
• Change in temperature occurs due to work only
• Change in temperature occurs due to work only
⚠ Adiabatic ≠ Isothermal
Temperature changes in adiabatic process
Temperature changes in adiabatic process
2️⃣ First Law Applied to Adiabatic Process
First Law:
ΔQ = ΔU + W
ΔQ = ΔU + W
Since ΔQ = 0
ΔU = −W
ΔU = −W
• Expansion → Work done by gas → Temperature decreases
• Compression → Work done on gas → Temperature increases
• Compression → Work done on gas → Temperature increases
3️⃣ Poisson’s Equation (Pressure–Volume Relation)
P Vγ = Constant
γ (gamma) = Cp / Cv
This relation is valid only for ideal gases
4️⃣ Other Important Adiabatic Relations
T Vγ−1 = Constant
Tγ P1−γ = Constant
These relations help in fast numerical solving
5️⃣ Graphical Comparison (JEE Favourite)
P–V Graph comparison:
• Adiabatic curve is steeper than isothermal curve
• Pressure drops faster in adiabatic expansion
• Pressure drops faster in adiabatic expansion
⚠ JEE often asks: Which curve is steeper?
6️⃣ Work Done in Adiabatic Process
W = (P₁V₁ − P₂V₂) / (γ − 1)
Derived using Poisson’s equation
7️⃣ Special Case: Free Expansion
• No work done (W = 0)
• No heat exchange (Q = 0)
• No heat exchange (Q = 0)
ΔU = 0 → ΔT = 0 (Ideal Gas)
⚠ Looks adiabatic but behaves differently
8️⃣ JEE Advanced Traps
⚠ Do not use PV = constant for adiabatic
⚠ Gamma depends on degrees of freedom
⚠ Adiabatic does NOT mean constant temperature
⚠ Gamma depends on degrees of freedom
⚠ Adiabatic does NOT mean constant temperature
👉 Next Page:
Page 10 – Cyclic Process, Heat Engine & Efficiency
Page 10 – Cyclic Process, Heat Engine & Efficiency
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