🔥 Thermodynamics – Stage 1

Page 9 : Adiabatic Process & Poisson’s Equations (JEE Core)

Adiabatic Process is one of the most frequently tested concepts in JEE.

1️⃣ What is an Adiabatic Process?

ΔQ = 0
• No heat enters or leaves the system
• Change in temperature occurs due to work only
⚠ Adiabatic ≠ Isothermal
Temperature changes in adiabatic process

2️⃣ First Law Applied to Adiabatic Process

First Law:
ΔQ = ΔU + W
Since ΔQ = 0

ΔU = −W
• Expansion → Work done by gas → Temperature decreases
• Compression → Work done on gas → Temperature increases

3️⃣ Poisson’s Equation (Pressure–Volume Relation)

P Vγ = Constant
γ (gamma) = Cp / Cv
This relation is valid only for ideal gases

4️⃣ Other Important Adiabatic Relations

T Vγ−1 = Constant
Tγ P1−γ = Constant
These relations help in fast numerical solving

5️⃣ Graphical Comparison (JEE Favourite)

P–V Graph comparison:
• Adiabatic curve is steeper than isothermal curve
• Pressure drops faster in adiabatic expansion
⚠ JEE often asks: Which curve is steeper?

6️⃣ Work Done in Adiabatic Process

W = (P₁V₁ − P₂V₂) / (γ − 1)
Derived using Poisson’s equation

7️⃣ Special Case: Free Expansion

• No work done (W = 0)
• No heat exchange (Q = 0)
ΔU = 0 → ΔT = 0 (Ideal Gas)
⚠ Looks adiabatic but behaves differently

8️⃣ JEE Advanced Traps

⚠ Do not use PV = constant for adiabatic
⚠ Gamma depends on degrees of freedom
⚠ Adiabatic does NOT mean constant temperature

👉 Next Page:
Page 10 – Cyclic Process, Heat Engine & Efficiency

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