🔥 Thermodynamics – Ultimate Recap (JEE Level)
Concepts • Laws • Traps • IIT Logic
1️⃣ Basic Definitions (Never Forget)
- System: Part under study
- Surroundings: Everything else
- State variable: Depends only on state (P, V, T, U, S)
- Path variable: Depends on process (Q, W)
2️⃣ Zeroth Law of Thermodynamics
If A is in thermal equilibrium with B and C separately,
then B and C are in equilibrium with each other.
Defines temperature.
Defines temperature.
3️⃣ First Law of Thermodynamics
ΔU = Q − W
- Heat added to system → Q positive
- Work done by system → W positive
- Internal energy is a state function
Cyclic process: ΔU = 0 ⇒ Q = W
4️⃣ Important Thermodynamic Processes
- Isothermal: T constant → ΔU = 0 → Q = W
- Adiabatic: Q = 0 → ΔU = −W
- Isochoric: V constant → W = 0 → Q = ΔU
- Isobaric: P constant → W = PΔV
5️⃣ Ideal Gas Essentials
- PV = nRT
- Internal energy depends only on temperature
- U = (f/2) nRT
- γ = CP / CV
6️⃣ Second Law of Thermodynamics
❌ Heat cannot completely convert into work in a cycle
❌ Heat does not flow from cold to hot without work
Kelvin–Planck: No 100% efficient engine
Clausius: Refrigerator needs work
Clausius: Refrigerator needs work
7️⃣ Entropy (Most Important for Advanced)
- dS = δQrev / T
- Entropy is a state function
- For isolated system: ΔS ≥ 0
- Reversible: ΔS = 0 (universe)
- Irreversible: ΔS > 0
8️⃣ Heat Engine & Refrigerator
- Efficiency = W / Qhot
- ηmax = 1 − Tcold/Thot
- Carnot engine is ideal and reversible
9️⃣ IIT JEE Traps & Golden Rules
- Entropy of universe never decreases
- ΔU = 0 does NOT mean Q = 0 or W = 0
- Heat & work are NOT state functions
- Check entropy before final answer
🔟 Exam-Day Strategy
- Identify process first
- Apply laws, not formulas blindly
- Eliminate options violating entropy
- Reversible = maximum efficiency
🏁 Thermodynamics Recap COMPLETE
✅ Ready for JEE Main & Advanced
✅ Ready for JEE Main & Advanced
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🔥 Thermodynamics – Objective Final Revision
Thermodynamics – Set 1
Set 2
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