🌡️ Thermodynamics – Stage 2
Page 2 : Advanced P–V Graphs & Work Calculation (JEE Advanced)
In JEE Advanced, P–V graphs are weapons.
If you read them correctly, half the problem is solved.
1️⃣ Work Done from P–V Graph (Core Rule)
Work done = Area under the P–V curve
(between initial and final volumes)
(between initial and final volumes)
👉 Larger enclosed area → more work done
2️⃣ Straight Line P–V Process (Hidden Favorite)
If pressure varies linearly with volume:
Work done = Area of trapezium
Work done = Area of trapezium
Formula:
W = (P₁ + P₂)/2 × (V₂ − V₁)
W = (P₁ + P₂)/2 × (V₂ − V₁)
⚠ Many students wrongly use isothermal formula here
3️⃣ Curved P–V Graphs (Estimation Technique)
If equation is unknown:
- Divide area into strips
- Approximate using rectangles/trapeziums
- Estimate logically (IIT accepts this)
4️⃣ Cyclic Processes (Very High Yield)
For a cyclic process:
ΔU = 0
ΔU = 0
Therefore:
Q = W
Q = W
👉 Net work = Area enclosed by loop
5️⃣ Direction of Loop = Sign of Work
- Clockwise loop → Work done by gas (+)
- Anticlockwise loop → Work done on gas (−)
⚠ This is a very common JEE Advanced trap
6️⃣ Comparing Different Paths (Same States)
Two paths, same initial & final states:
- ΔU is same
- Work is different
- Heat exchanged is different
👉 Path matters for Q and W, not for ΔU
7️⃣ Visual Shortcut (Toppers’ Trick)
Before calculation, ask:
- Is expansion more at high pressure?
- Which path encloses more area?
👉 Bigger area always wins
8️⃣ IIT-Level Mistakes to Avoid
❌ Ignoring graph scale
❌ Forgetting direction of cycle
❌ Applying wrong process formula
❌ Forgetting direction of cycle
❌ Applying wrong process formula
✅ Stage 2 – Page 2 Complete
👉 Next: Stage 2 – Page 3 : First Law in Multi-Process Systems
👉 Next: Stage 2 – Page 3 : First Law in Multi-Process Systems
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